Denisov, E. T. published the artcileKinetic parameters for the forward and reverse reactions of the tert-butoxyl radical with phenols, Computed Properties of 14703-69-6, the publication is Kinetika i Kataliz (1993), 34(3), 424-9, database is CAplus.
Parameters of the parabolic transition state model (2 intersecting unperturbed potential energy curves) for H-abstraction reaction of Me3CO• with phenols were evaluated from exptl. kinetic data reported in the literature. Constancy of the bre parameter for classes of sterically hindered and nonhindered phenols permitted calculation of forward and reverse rate constants of 99 phenols with Me3CO• at 333 K.
Kinetika i Kataliz published new progress about 14703-69-6. 14703-69-6 belongs to alcohols-buliding-blocks, auxiliary class Amine,Benzene,Phenol, name is 3-(Methylamino)phenol, and the molecular formula is C7H9NO, Computed Properties of 14703-69-6.
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