Cabrera-Afonso, Maria J. published the artcileSite-selective Oxidative Dearomatization of Phenols and Naphthols into ortho-Quinols or Epoxy ortho-Quinols using Oxone as the Source of Dimethyldioxirane, Computed Properties of 86-48-6, the publication is Advanced Synthesis & Catalysis (2019), 361(19), 4468-4473, database is CAplus.
A novel reactivity of dimethyldioxirane generated in-situ from oxone and acetone, with substituted phenols and naphthols was reported. This methodol. allowed the synthesis of ortho-quinols or epoxy ortho-quinols from a site-selective oxidative dearomatization process with good yields under very mild conditions. A short total synthesis of natural product lacinilene C Me ether was also described using this process as the key step.
Advanced Synthesis & Catalysis published new progress about 86-48-6. 86-48-6 belongs to alcohols-buliding-blocks, auxiliary class Organic Pigment,Natural product, name is 1-Hydroxy-2-naphthoic acid, and the molecular formula is C11H8O3, Computed Properties of 86-48-6.
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