Salomon, Marcel Ahijado published the artcileStepwise oxygenation of pinacolborane by a rhodiumperoxo complex: detection of an intermediate metal borate and perborate, Quality Control of 25240-59-9, the publication is Angewandte Chemie, International Edition (2008), 47(46), 8867-8871, database is CAplus and MEDLINE.
Acting as go-between: A Rh borate and perborate were identified as intermediates in the Rh-mediated oxygenation of pinacolborane (HBpin). The Rh(III)-peroxo complex reacts with the Lewis acidic B compound HBpin by O transfer from the Rh center to HBpin to give a Rh(I) species. The reaction sequence might play a crucial role in the homocoupling of boronic acid.
Angewandte Chemie, International Edition published new progress about 25240-59-9. 25240-59-9 belongs to alcohols-buliding-blocks, auxiliary class Boronic acid and ester,Boronic Acids,Boronate Esters, name is 4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-ol, and the molecular formula is C6H13BO3, Quality Control of 25240-59-9.
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