Kesavan, Arunachalam’s team published research in Chemical Communications (Cambridge, United Kingdom) in 58 | CAS: 4410-99-5

Chemical Communications (Cambridge, United Kingdom) published new progress about 4410-99-5. 4410-99-5 belongs to alcohols-buliding-blocks, auxiliary class Thiol,Benzene, name is 2-Phenylethanethiol, and the molecular formula is C8H10S, Safety of 2-Phenylethanethiol.

Kesavan, Arunachalam published the artcileCatalytic enantioselective oxysulfenylation of o-vinylanilides, Safety of 2-Phenylethanethiol, the publication is Chemical Communications (Cambridge, United Kingdom) (2022), 58(2), 282-285, database is CAplus and MEDLINE.

Tf2NH-Assisted BINAM-derived thiophosphoramide catalysis was accomplished for the enantioselective oxysulfenylation of o-vinylanilides with N-(aryl/alkylthio)imides. The developed reaction offered access to diverse substituted aryl/alkylthio tethered 3,1-benzoxazines I [R = 6-MeO, 6-Cl, 7-Cl, 8-MeO, 8-BzO; R1 = Ph, 4-EtC6H4, 4-FC6H4, etc.; Ar = Ph, Bn, 2-MeC6H4, etc.; Ar1 = Ph, 4-MeC6H4, 3-IC6H4, etc.] in excellent yields and enantiomeric ratios. Furthermore, synthetic applications of benzoxazines and aryl/alkylthio moieties and a transition state model for the observed enantioselectivity were also discussed.

Chemical Communications (Cambridge, United Kingdom) published new progress about 4410-99-5. 4410-99-5 belongs to alcohols-buliding-blocks, auxiliary class Thiol,Benzene, name is 2-Phenylethanethiol, and the molecular formula is C8H10S, Safety of 2-Phenylethanethiol.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts