Visible light promoted polyhalomethylation of alkenes: alkylation and cyclization was written by Wang, Tong-Lin;Zhang, Bo-Sheng;Liu, Jing-Jiang;Liu, Xiao-Jun;Wang, Xi-Cun;Quan, Zheng-Jun. And the article was included in Organic Chemistry Frontiers in 2022.Electric Literature of C10H22O The following contents are mentioned in the article:
A visible light promoted carbochloromethylation of 2-bromomethyl acrylates BrCH2CH(=CH2)C(O)OR1 (R1 = Me, cyclopentyl, (5S)-1,7,7-trimethylbicyclo[3.1.1]heptan-6-yl, etc.), N-arylmethacrylamides R2N(CH3)C(O)CH(=CH2)CH3 (R2 = Ph, pyridin-2-yl, 4-chlorophenyl, etc.), and a series of trihalomethyl substituted allylic acid esters R1C(O)OCH(=CH2)CH2R3 (R3 = trichloromethyl, dichloromethyl, 1,1,2,2-tetrachloroethyl, etc.) and indolone derivatives I (R4 = Me, Et, Cl, etc.) and 1,3-dimethyl-3-(2,2,2-trichloroethyl)-1,3-dihydro-2H-benzo[g]indol-2-one/pyrrolo[2,3-b]pyridin-2-one were reported. The reaction used common and inexpensive chloroform and tribromomethane as trihalomethyl reagents R3H, iodobenzene diacetate (PIDA) as an oxidant and Eosin Y as a photocatalyst. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Electric Literature of C10H22O).
3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Grignard and organolithium reagents are powerful tools for organic synthesis, and the most common products of their reactions are alcohols.Electric Literature of C10H22O
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts