A general and efficient Mn-catalyzed acceptorless dehydrogenative coupling of alcohols with hydroxides into carboxylates was written by Shao, Zhihui;Wang, Yujie;Liu, Yaqian;Wang, Qian;Fu, Xiaoling;Liu, Qiang. And the article was included in Organic Chemistry Frontiers in 2018.Formula: C10H22O The following contents are mentioned in the article:
Herein, a sustainable method was developed for the synthesis of carboxylic acids RCO2H [R = Me, Ph, 3-pyridyl, etc.] via manganese-catalyzed acceptorless dehydrogenation of alcs. generating H2 as the sole byproduct. A wide range of carboxylic acids were synthesized with high yields and excellent functional group tolerance. The reaction proceeded selectively in the presence of a well-defined manganese pincer complex at a very low catalyst loading. Mechanistic studies including control experiments, NMR spectroscopy and X-ray crystallog. identified the resting state and key intermediates in the catalytic cycle. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Formula: C10H22O).
3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Grignard and organolithium reagents are powerful tools for organic synthesis, and the most common products of their reactions are alcohols.Formula: C10H22O
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts