On the Use of Polyelectrolytes and Polymediators in Organic Electrosynthesis was written by Schille, Benjamin;Giltzau, Niels Ole;Francke, Robert. And the article was included in Angewandte Chemie, International Edition in 2018.Recommanded Product: 106-21-8 The following contents are mentioned in the article:
Although organic electrosynthesis is generally considered to be a green method, the necessity for excess amounts of supporting electrolyte constitutes a severe drawback. Also, the employment of redox mediators results in an addnl. separation problem. In this context, the authors have explored the applicability of soluble polyelectrolytes and polymediators with the TEMPO-mediated transformation of alcs. into carbonyl compounds as a test reaction. Catalyst benchmarking based on cyclic voltammetry studies indicated that the redox-active polymer can compete with molecularly defined TEMPO species. Alc. oxidation was also highly efficient on a preparative scale, and the authors’ polymer-based approach allowed for the separation of both mediator and supporting electrolyte in a single membrane filtration step. Also, both components can be reused multiple times. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Recommanded Product: 106-21-8).
3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Recommanded Product: 106-21-8
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts