On the nitroxide mediated polymerization of methacrylates derived from bio-sourced terpenes in miniemulsion, a step towards sustainable products was written by Noppalit, Sayrung;Simula, Alexandre;Billon, Laurent;Asua, Jose M.. And the article was included in Polymer Chemistry in 2020.Formula: C10H22O The following contents are mentioned in the article:
The incorporation of monomers derived from natural resources into industrially viable block copolymers is a long-standing problem that has not been appropriately solved yet due to a combination of issues that include the use of toxic solvents, relatively expensive control agents, and the need of intermediate purification steps. This study aims at overcoming these limitations. Nitroxide mediated polymerization of methacrylates synthesized from bio-resourced terpenes is carried out in miniemulsion using Dispolreg 007, an alkoxyamine that is produced through a cost effective and easily scalable synthetic route. Well-defined poly(tetrahydrogeraniol methacrylate)-b-poly(cyclademol methacrylate) diblock copolymers are obtained at high monomer conversions (>90%), without the need for intermediate purification steps. The resulting “soft”/”hard” diblock copolymers show good potential as waterborne pressure-sensitive adhesives. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Formula: C10H22O).
3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Formula: C10H22O
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts