Syntheses, crystal structures and spectroscopic characterization of two new octahedral nickel(II) complexes of a Schiff base ligand derived from pyridoxal and 2-(pyrid-2-yl)ethylamine was written by Mandal, Senjuti;Modak, Ritwik;Sikdar, Yeasin;Naskar, Barnali;Goswami, Sanchita. And the article was included in Journal of Molecular Structure in 2014.Product Details of 65-22-5 The following contents are mentioned in the article:
Two new coordination compounds based on ONN donor Schiff base ligand derived from pyridoxal and 2-(pyrid-2-yl)ethylamine, namely {[Ni(HL)(H2O)2](ClO4)2}∞ (1) and [Ni(HL)(H2O)(SCN)2] (2) have been synthesized and structurally characterized by single-crystal x-ray diffraction along with other phys. techniques, including elemental anal., IR spectra and UV-visible studies. X-ray studies suggest that both 1 and 2 are mononuclear nickel(II) complexes and exhibit distorted octahedral geometry. In these compounds the pyridoxal based Schiff base ligand displays different coordination modes constructing various architectures. This study involved multiple reactions and reactants, such as 3-Hydroxy-5-(hydroxymethyl)-2-methylisonicotinaldehyde hydrochloride (cas: 65-22-5Product Details of 65-22-5).
3-Hydroxy-5-(hydroxymethyl)-2-methylisonicotinaldehyde hydrochloride (cas: 65-22-5) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Product Details of 65-22-5
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts