Catalytic Reductions Without External Hydrogen Gas: Broad Scope Hydrogenations with Tetrahydroxydiboron and a Tertiary Amine was written by Korvinson, Kirill A.;Akula, Hari K.;Malinchak, Casina T.;Sebastian, Dellamol;Wei, Wei;Khandaker, Tashrique A.;Andrzejewska, Magdalena R.;Zajc, Barbara;Lakshman, Mahesh K.. And the article was included in Advanced Synthesis & Catalysis in 2020.Synthetic Route of C10H22O The following contents are mentioned in the article:
Aryl bromides, iodides, chlorides, and triflates, benzylic halides and ethers, benzyl carbamates, alkenes, alkynes, azides, and aldehydes underwent reductive cleavage, hydrogenation, and reduction reactions using B2(OH)4 as reductant in the presence of Pd/C and 4-methylmorpholine. Aryl dihalides containing two different halogen atoms underwent selective reduction, with reduction of I favored over reduction of Br and Cl, and Br reduction favored over the reduction of Cl. Cyano groups were unaffected, but nitro group and ketones underwent reduction to a low extent. B2(OD)4 and N,N-bis(methyl-d3)pyridin-4-amine (DMAP-d6) were used as reagents for the reductive deuteration of aryl halides. Hydrogen gas has been observed to form with this reagent combination. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Synthetic Route of C10H22O).
3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Synthetic Route of C10H22O
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts