Hexnut[12]arene and its derivatives: Synthesis, host-guest properties, and application as nonporous adaptive crystals was written by Cheng, Jian;Gao, Bingbing;Tang, Hao;Sun, Zhihong;Xu, Linxian;Wang, Lingyun;Cao, Derong. And the article was included in Science China: Chemistry in 2022.SDS of cas: 620-92-8 The following contents are mentioned in the article:
Hexnut[12]arene (HN[12]) and its derivatives, a new class of sixfold macrocyclic arenes, were designed and synthesized in reasonable yield by a one-pot reaction at room temperature using dimethoxymethane as a methylene source. HN[12], which bears a large, sym., and rigid cavity, was easily functionalized at both the methylene bridges and the hydroquinone units. A water-soluble fluorescent HN[12] was synthesized and used as a host to encapsulate benzyl viologen dichloride in water with a high binding affinity of (3.4 ± 0.2) x 106 M-1. The nonporous adaptive crystal (NAC) of HN[12] was found to capture not only inorganic mols. (iodine) but also trace amounts of large organic mols. (basic fuchsine) from water, which greatly expanded the scope of NACs for adsorption. This study involved multiple reactions and reactants, such as 4,4′-Methylenediphenol (cas: 620-92-8SDS of cas: 620-92-8).
4,4′-Methylenediphenol (cas: 620-92-8) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Grignard and organolithium reagents are powerful tools for organic synthesis, and the most common products of their reactions are alcohols.SDS of cas: 620-92-8
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