Non-thermal microwave effects in radical polymerization of bio-based terpenoid (meth)acrylates was written by Castagnet, Thibault;Agirre, Amaia;Ballard, Nicholas;Billon, Laurent;Asua, Jose M.. And the article was included in Polymer Chemistry in 2020.Application In Synthesis of 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:
Microwave-assisted polymerization represents an opportunity to develop efficient polymerization strategies for the synthesis of (bio)macromols. with improved properties. The possibilities will increase tremendously if non-thermal microwave effects, i.e. effect of microwaves on the kinetic constants, are operative, because we can increase at the same time conversion and mol. weight This work investigates these effects in the free radical polymerization of bio-based terpenoid (meth)acrylates finding that terpenoid acrylates present a strong non-thermal microwave effect, whereas the methacrylate ones do not show any effect. The reasons for these findings are discussed and the results compared with the apparently conflicting literature. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Application In Synthesis of 3,7-Dimethyloctan-1-ol).
3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Application In Synthesis of 3,7-Dimethyloctan-1-ol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts