Shubhashish, Shubhashish published the artcileSynthesis of Highly Porous Metal Oxide Nanoparticles for Adsorption Applications, HPLC of Formula: 111-29-5, the publication is ACS Applied Nano Materials (2022), 5(5), 7078-7091, database is CAplus.
Herein, we report a general and straightforward synthesis method for large-pore highly mesoporous metal oxide nanoparticles via a modified inverse micelle formation. The role of diols as solvents has been demonstrated and extended to other metal oxides using ethylene glycol. After scanning most of the metals from the periodic table, magnesium and calcium from the s-block; tin from the p-block; vanadium, nickel, zinc, zirconium, and hafnium from the d-block; and lanthanum and cerium from the f-block elements, all these have been successfully synthesized as large-pore-diameter metal oxides. Because of thermodn. stability of chelate formation, ethylene glycol, 1,3-propanediol, 1,4-butanediol, and 1,5-pentanediol give a higher pore diameter, whereas a further increase in the diol carbon chain (1,6-hexanediol and 1,12-dodecanediol) leads to pore contraction. By varying the synthesis temperature, the effect of viscosity on the pore diameter has also been demonstrated. Potential applications of oxides of magnesium have been tested for carbon dioxide capture and adsorption of macromols. such as proteins and lipids and small mols. such as curcumin, dopamine, and sucrose. As predicted, larger-pore-diameter and higher-pore-volume mesoporous magnesium oxide shows higher carbon dioxide capture and adsorption compared to com. magnesium oxide. A mechanism for the higher pore diameters of mesoporous metal oxide nanomaterials has been proposed based on the results and previous reported literature studies.
ACS Applied Nano Materials published new progress about 111-29-5. 111-29-5 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic hydrocarbon chain,Alcohol,Ploymers, name is Pentane-1,5-diol, and the molecular formula is C10H6F17N, HPLC of Formula: 111-29-5.
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