Muraskova, Viera et al. published their research in Polyhedron in 2021 | CAS: 65-22-5

3-Hydroxy-5-(hydroxymethyl)-2-methylisonicotinaldehyde hydrochloride (cas: 65-22-5) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.SDS of cas: 65-22-5

Iron(III) and cobalt(III) complexes with pentadentate pyridoxal Schiff base ligand – structure, spectral, electrochemical, magnetic properties and DFT calculations was written by Muraskova, Viera;Eigner, Vaclav;Dusek, Michal;Sedmidubsky, David. And the article was included in Polyhedron in 2021.SDS of cas: 65-22-5 The following contents are mentioned in the article:

Three complexes, [FeLCl]Cl·H2O, [Co2L2H3O2]Cl·4.8H2O, and [CoLN3], where L2- is the dianion of an asym. propyl-Et pentadentate Schiff base ligand condensed from pyridoxal and N-(2-aminoethyl)propane-1,3-diamine, have been synthesized and characterized by elemental anal., FTIR and mass spectroscopy. Crystal structures of the complexes along with the Schiff base were determined by x-ray diffraction. 1HNMR spectrum of the Schiff base has been obtained. The coordination polyhedra of all three complexes can be expressed as distorted octahedra. Magnetic investigations of [FeLCl]Cl·H2O complex confirmed high-spin state over the whole temperature range (5-300 K) and allowed the evaluation of the axial zero-field splitting (ZFS) parameter D = -0.97 cm-1, intermol. exchange parameter zj ́= -0.88 cm-1 and temperature-independent paramagnetism χTIM = 0.00025 cm3mol-1. The low-spin state of Co(III) was stabilized in diamagnetic [Co2L2H3O2]Cl·4.8H2O and [CoLN3] complexes. Redox potentials of the Schiff base and the complexes were investigated by cycling voltammetry on the GC electrode in dry acetonitrile. The exptl. magnetic properties of the complexes [FeLCl]Cl·H2O and [CoLN3] were compared with the theor. ones calculated using d. functional theory (DFT). This study involved multiple reactions and reactants, such as 3-Hydroxy-5-(hydroxymethyl)-2-methylisonicotinaldehyde hydrochloride (cas: 65-22-5SDS of cas: 65-22-5).

3-Hydroxy-5-(hydroxymethyl)-2-methylisonicotinaldehyde hydrochloride (cas: 65-22-5) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.SDS of cas: 65-22-5

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts