Effects of monomer rigidity on microstructures and properties of novel polyamide thin-film composite membranes prepared through interfacial polymerization for pervaporation dehydration was written by Lee, Jen-Yu;Huang, Ting-Yi;Belle Marie Yap Ang, Micah;Huang, Shu-Hsien;Tsai, Hui-An;Jeng, Ru-Jong. And the article was included in Journal of Membrane Science in 2022.COA of Formula: C13H12O2 The following contents are mentioned in the article:
In this study, thin-film composite (TFC) membranes were produced through interfacial polymerization between diamine and trimesoyl chloride on a polyetherimide (PEI) support. The TFC membranes with different diamines, 4,4′-((propane-2,2-diylbis(4,1-phenylene))bis(oxy))dianiline (BAPP), 4,4′-((methylene bis(4,1-phenylene))bis(oxy))dianiline (MPDA), and 6,6′-bis(4-aminopheoxy)-4,4,4′,4′,7,7′-hexamethyl-2,2′-spirobichroman (SBC), were denoted as TFCPEI/B, TFCPEI/M, and TFCPEI/S, resp. These three aromatic diamines have different central moieties that affect reactivity during the interfacial polymerization reaction. The crosslinking degree of the TFC membranes increased in the following order: TFCPEI/S < TFCPEI/M < TFCPEI/B. Positron annihilation lifetime spectroscopy anal. also unveils that TFCPEI/B had the lowest free volume These results reveal that the appropriate steric structure of the diamine mols. can create less compact structure without impeding the formation of the crosslinked polyamide selective layer. Moreover, the TFCPEI/B membrane had a flux of approx. 705±46 g•m-2 h-1, and the water concentration in the permeate was maintained at approx. 99.8% at 25° during the 70% isopropanol solution dehydration. Furthermore, the TFCPEI/B membrane can be operated under broad operating conditions and possesses high long-term stability. This study involved multiple reactions and reactants, such as 4,4′-Methylenediphenol (cas: 620-92-8COA of Formula: C13H12O2).
4,4′-Methylenediphenol (cas: 620-92-8) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.COA of Formula: C13H12O2
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