Zhu, Kaili; Xu, Xudong; Xu, Mengqiu; Deng, Ping; Wu, Wenbo; Ye, Wei; Weng, Zihui; Su, Yue; Wang, Huijie; Xiao, Fei; Fang, Zeping; Gao, Peng published their research in ChemElectroChem in 2021. The article was titled 《One-Pot Synthesis of Tensile-Strained PdRuCu Icosahedra toward Electrochemical Hydrogenation of Alkene》.Related Products of 821-41-0 The article contains the following contents:
Electrochem. hydrogenation (ECH) uses electricity to drive proton (H+) reduction for hydrogenation, which can greatly reduce energy supply and environmental pollution, representing an ideal alternative to traditional thermal hydrogenation. In this work, we put forward tensile-strained PdRuCu alloy to promote ECH. Tensile strain promotes the adsorption of C=C by changing the d-band center. Meanwhile, alloying Ru and Cu into Pd lattice facilitates hydrogenation by weakening Pd-H bonding. Therefore, PdRuCu icosahedra display excellent ECH performance of 2-methyl-3-buten-2-ol (MBE) with specific activity of 227.4μmolMBE nm-2 min-1 at -0.3 V vs. reversible hydrogen electrode (RHE), about 16.1 and 10.5 times higher than that of com. Pd/C and Ru/C, resp. In addition, PdRuCu icosahedra was excellent in the scaling up of substrate concentration combined with anisyl alc. oxidation to produce high-value added anisaldehyde at anode. This work provides a guideline for the rational design of highly active and durable metallic catalyst in ECH. The experimental process involved the reaction of 5-Hexen-1-ol(cas: 821-41-0Related Products of 821-41-0)
5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Related Products of 821-41-0
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts