《Inhibition and enhancement of luminol-KIO4-H2O2 chemiluminescence by organic compounds》 was written by Xu, Hong. Electric Literature of C10H14O2 And the article was included in Faguang Xuebao on August 31 ,2006. The article conveys some information:
The inhibition and enhancement of liquid phase CL by organic compounds are of considerable interests in anal. chem. because they can be used for the sensitive detection of numerous compounds The mechanism of inhibition and enhancement is not fully understood and discovery of new enhancers and inhibitors is usually achieved in empirical fashion by trail and error. Although there are reports in literatures concerning the use of luminol-KIO4-H2O2 CL for determination of hydrogen peroxide, glucose and ascorbic acid, the effect of aromatic compounds on luminol-KIO4-H2O2 CL has not been studied systematically. The effects of 36 organic compounds on the luminol-KIO4-H2O2 system chemiluminescence (CL) were studied under different pH conditions of luminol solution The CL signal was detected with flow injection chemiluminescence system (Xi’an Ruimai Electronic Technol. Co.Ltd, China) consisted of model IFFM-D peristaltic pump, mixing tee, model IFFS-A CL detector equipped with glass coil (used as reaction coil and detection cell), photomultiplier, and IBM compatible microcomputer. It was found that most of tested compounds could inhibit or enhance CL intensity. The activities of such inhibitors or enhancers were related to pH value of CL system and number and position of functional groups such as -OH and -NH2 on aromatic ring and property of substituent group, electron delocalization and steric hindrance. The CL spectra and UV-visible absorption spectra were studied and mechanism for CL inhibition and enhancement was also discussed. The mechanism for such inhibition or enhancement of organic compounds is most likely due to the reactions between inhibitors or enhancers and radical intermediates of CL reactions. The possibility of anal. applications was explored based on CL inhibition or enhancement. The results demonstrated that numerous compounds are detectable at ng.mL∓1 level. In addition to this study using 4-Butylbenzene-1,2-diol, there are many other studies that have used 4-Butylbenzene-1,2-diol(cas: 2525-05-5Electric Literature of C10H14O2) was used in this study.
4-Butylbenzene-1,2-diol(cas: 2525-05-5) belongs to organoboron compounds. Organoboron compounds are versatile intermediates and as such are some of the most important classes of reagents in modern organic chemistry. Organoboron compounds are less toxic than organostannane reagents, and unlike alkynylzinc and magnesium, many organoboron compounds possess remarkable oxidative and thermal stabilities. Electric Literature of C10H14O2
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