In 2019,Synlett included an article by Miura, Tomoya; Moriyama, Daisuke; Funakoshi, Yuuta; Murakami, Masahiro. Computed Properties of C6H12O. The article was titled 《Photoinduced 1,2-Hydro(cyanomethylation) of Alkenes with a Cyanomethylphosphonium Ylide》. The information in the text is summarized as follows:
An efficient method was developed for the 1,2-hydro(cyanomethylation) of alkenes, in which a cyanomethyl radical species was generated from a cyanomethylphosphonium ylide by irradiation with visible light in the presence of an iridium complex, a thiol, and ascorbic acid. The cyanomethyl radical species then adds across the C:C double bond of an alkene to form an elongated alkyl radical species that accepts a hydrogen atom from the thiol to produce an elongated aliphatic nitrile. The ascorbic acid acts as the reductant to complete the catalytic cycle. In the experimental materials used by the author, we found 5-Hexen-1-ol(cas: 821-41-0Computed Properties of C6H12O)
5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Computed Properties of C6H12O
Referemce:
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Alcohols – Chemistry LibreTexts