Li, Xin; He, Songtao; Song, Qiuling published their research in Organic Letters in 2021. The article was titled 《Diethylzinc-Mediated Radical 1,2-Addition of Alkenes and Alkynes》.Category: alcohols-buliding-blocks The article contains the following contents:
A novel diethylzinc-mediated radical 1,2-addition of perfluoroalkyl iodides to unactivated alkenes and alkynes was presented, which demonstrates a novel way to generate an Et difluoroacetate radical. This method was highly efficient and gives full conversions of the substrates, high yields of the products and negligible byproducts and requires no column chromatog. purifications. The mild conditions enable this protocol to exhibited excellent functional group compatibility. The experimental process involved the reaction of 5-Hexen-1-ol(cas: 821-41-0Category: alcohols-buliding-blocks)
5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Category: alcohols-buliding-blocks
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts