In 2019,Synthesis included an article by Kawano, Teruhiro; Watari, Ryo; Kayaki, Yoshihito; Ikariya, Takao. SDS of cas: 100-55-0. The article was titled 《Catalytic Hydrogenation of Carboxamides with a Bifunctional Cp*Ru Catalyst Bearing an Imidazol-2-ylidene with a Protic Aminoethyl Side Chain》. The information in the text is summarized as follows:
Synthesis of a Cp*Ru complex bearing an NH2-functionalized N-heterocyclic carbene (C-NH) I (R = CH3) was achieved by treatment of Cp*RuBr(isoprene) with an equimolar amount of a silver complex, which was generated from Ag2O and 1-(2-aminoethyl)-3-methylimidazolium bromide, in CH3CN at room temperature The new Cp*RuBr(C-NH) complex I showed a higher catalytic performance than the related Cp*RuCl(P-NH) and Cp*RuCl(N-NH) complexes. In the reaction of N-arylcarboxamides R1C(O)NR2R3 (R1 = H, C6H5, pyridin-3-yl; R2 = R3 = CH3; R2 = H, R3 = C6H5; R2R3 = -C(O)(CH2)3-, etc.), the amine products R2R3NH were obtained in satisfactory yields under mild temperature conditions. In the part of experimental materials, we found many familiar compounds, such as 3-Pyridinemethanol(cas: 100-55-0SDS of cas: 100-55-0)
3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is widely used in the precursor to agrochemicals and pharmaceuticals. Also, it is used as an important reagent and organic solvent.SDS of cas: 100-55-0
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