《Visible-Light-Induced Nickel-Catalyzed Cross-Coupling with Alkylzirconocenes from Unactivated Alkenes》 was published in Chem in 2020. These research results belong to Gao, Yadong; Yang, Chao; Bai, Songlin; Liu, Xiaolei; Wu, Qingcui; Wang, Jing; Jiang, Chao; Qi, Xiangbing. Application of 821-41-0 The article mentions the following:
Visible-light-induced single nickel-catalyzed C(sp3)-C(sp3), C(sp3)-C(sp2) and C(sp3)-C(sp) cross-coupling reactions were reported using alkylzirconocenes, which were easily generated in-situ from terminal or internal unactivated alkenes through hydrozirconation and chain walking. This method was mild and applicable for a large range of substrates including primary, secondary, tertiary alkyl, aryl, alkenyl, alkynyl halides and a variety of alkenes. Mechanistic studies suggested a novel nickel-catalyzed radical cross-coupling pathway, which represented the first visible-light-induced transformation of alkylzirconocenes. The experimental process involved the reaction of 5-Hexen-1-ol(cas: 821-41-0Application of 821-41-0)
5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Application of 821-41-0
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