ãRhodium-catalyzed regioselective C(sp2)-H bond activation reactions of N-(hetero)aryl-7-azaindoles and cross-coupling with α-carbonyl sulfoxonium ylidesã?was written by Tian, Yan; Kong, Xian-Qiang; Niu, Jie; Huang, Yi-Bo; Wu, Zhao-Hua; Xu, Bo. SDS of cas: 7748-36-9 And the article was included in Tetrahedron Letters in 2020. The article conveys some information:
A protocol for rhodium-catalyzed C(sp2)-H bond activation reactions of N-(hetero)aryl-7-azaindoles and cross-coupling with α-carbonyl sulfoxonium ylides were described. In the C-H activation reaction, the 7-azaindole moiety acted as a directing group which results in high regioselectivity. The protocol features excellent chem. yields and good functional group tolerance. In the experiment, the researchers used Oxetan-3-ol(cas: 7748-36-9SDS of cas: 7748-36-9)
Oxetan-3-ol(cas: 7748-36-9) is used as a reagent in the synthesis of 5-fluoro-4,6-dialkoxypyrimidine GPR119 agonists. It is also used as a reagent in the synthesis of cyclic sulfone hydroxyethylamines as potent and selective β-site APP-cleaving enzyme 1 (BACE1) inhibitors.SDS of cas: 7748-36-9
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