Category: alcohols-buliding-blocksOn November 20, 2020 ,ãPhotochemical C-H Silylation and Hydroxymethylation of Pyridines and Related Structures: Synthetic Scope and Mechanismsã?appeared in ACS Catalysis. The author of the article were Rammal, Fatima; Gao, Di; Boujnah, Sondes; Hussein, Aqeel A.; Lalevee, Jacques; Gaumont, Annie-Claude; Morlet-Savary, Fabrice; Lakhdar, Sami. The article conveys some information:
Described herein is an efficient approach for C-H silylation and hydroxymethylation of pyridines and related heterocycles by the combination of silanes or methanol with readily available N-methoxypyridinium ions with a low catalyst loading (2 mol %) under blue light irradiation The synthetic importance of the developed reactions is demonstrated by the synthesis of biol. relevant compounds ESR spectroscopy, quantum yield measurements, and d.-functional theory calculations allowed to understand reaction mechanisms of both photocatalytic reactions. In the experiment, the researchers used many compounds, for example, (4-Phenylpyridin-2-yl)methanol(cas: 55218-73-0Category: alcohols-buliding-blocks)
(4-Phenylpyridin-2-yl)methanol(cas: 55218-73-0) belongs to hydroxy-containing compounds. Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this functional group.Category: alcohols-buliding-blocks Organic compounds, which are often poorly soluble in water, become water-soluble when they contain two or more hydroxy groups, as illustrated by sugars and amino acid.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts