HPLC of Formula: 873-75-6In 2019 ,ãPolymer-Anchored Bifunctional Pincer Catalysts for Chemoselective Transfer Hydrogenation and Related Reactionsã?appeared in ChemSusChem. The author of the article were Mujahed, Shrouq; Valentini, Federica; Cohen, Shirel; Vaccaro, Luigi; Gelman, Dmitri. The article conveys some information:
A series of polymer-supported cooperative PC(sp3)P pincer catalysts was synthesized and characterized. Their catalytic activity in the acceptorless dehydrogenative coupling of alcs. to form β-alkylated ketones and the transfer hydrogenation of aldehydes to form benzyl alcs. using formic acid as a hydrogen source was investigated. This comparative study, examining homogeneous and polymer-tethered species, proved that carefully designing a link between the support and the catalytic moiety, which takes into consideration the mechanism underlying the target transformation, might lead to superior heterogeneous catalysis. The experimental process involved the reaction of (4-Bromophenyl)methanol(cas: 873-75-6HPLC of Formula: 873-75-6)
(4-Bromophenyl)methanol(cas: 873-75-6) undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls.HPLC of Formula: 873-75-6 It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde.
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