In 2017,Li, Lei; Gong, Tianjun; Lu, Xi; Xiao, Bin; Fu, Yao published 《Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes》.Nature Communications published the findings.HPLC of Formula: 78782-17-9 The information in the text is summarized as follows:
Organoboron compounds play an irreplaceable role in synthetic chem. and the related transformations based on the unique reactivity of C-B bond are potentially the most efficient methods for the synthesis of organic mols. The synthetic importance of multiboron compounds in C-C bond formation and function transformation reactions is growing and the related borations of activated or nonactivated alkenes have been developed recently. However, introducing directly two boron moieties into the terminal sites of alkenes giving 1,1-diborylalkanes in a catalytic fashion has not been explored yet. Here authors describe a synthetic strategy of 1,1-diborylalkanes via a Ni-catalyzed 1,1-diboration of readily available terminal alkenes. This methodol. shows high level of chemoselectivity and regioselectivity and can be used to convert a large variety of terminal alkenes, such as vinylarenes, aliphatic alkenes and lower alkenes, to 1,1-diborylalkanes.Bis[(pinacolato)boryl]methane(cas: 78782-17-9HPLC of Formula: 78782-17-9) was used in this study.
Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds. Organoboron compounds have been a cornerstone of synthetic transformations for decades. Areas such as boron-containing catalysts, metalate chemistry, photoredox methods, and boryl anions have brought significant new developments in understanding and provided new reactivity upon.HPLC of Formula: 78782-17-9
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