He, Yu-Tao; Li, Li-Xuan; Lin, Xiaohong; Hou, Bao-Long; Li, Chuang-Chuang published an article on January 14 ,2022. The article was titled ãSynthesis of Various Bridged Ring Systems via Rhodium-Catalyzed Bridged (3+2) Cycloadditionsã? and you may find the article in Organic Letters.Application of 57044-25-4 The information in the text is summarized as follows:
Here, the authors describe the rhodium-catalyzed bridged [3+2]-cycloaddition cascade reactions of N-sulfonyl-1,2,3-triazoles, which allowed the efficient diastereoselective construction of various functionalized and synthetically challenging bridged ring systems. This simple, direct transformation had a broad substrate scope and excellent functional group tolerance. The highly strained polycyclic bicyclo[2.2.2]octa[b]indole core of fruticosine was synthesized efficiently using this methodol. The experimental process involved the reaction of (R)-Oxiran-2-ylmethanol(cas: 57044-25-4Application of 57044-25-4)
(R)-Oxiran-2-ylmethanol(cas: 57044-25-4) is a chiral building block used to construct an epoxyvinyl iodide intermediate in a synthesis of a furanocembrane, a marine natural product.Application of 57044-25-4
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