Edelstein, Emma K.’s team published research in Synlett in 2018 | CAS: 78782-17-9

Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds. Organoboron compounds have been a cornerstone of synthetic transformations for decades. Areas such as boron-containing catalysts, metalate chemistry, photoredox methods, and boryl anions have brought significant new developments in understanding and provided new reactivity upon.Electric Literature of C13H26B2O4

In 2018,Edelstein, Emma K.; Grote, Andrea C.; Palkowitz, Maximilian D.; Morken, James P. published 《A Protocol for Direct Stereospecific Amination of Primary, Secondary, and Tertiary Alkylboronic Estersã€?Synlett published the findings.Electric Literature of C13H26B2O4 The information in the text is summarized as follows:

Primary, secondary, and (non-benzylic) tertiary alkylboronic acids underwent stereoselective (stereospecific) amination with O-methylhydroxylamine and potassium-tert-butoxide in toluene/THF to yield either Boc-protected primary or secondary amines or Boc-protected or free tertiary amines; nonracemic secondary and tertiary alkylamines were prepared in >98% enantiospecificities from the corresponding boronates.Bis[(pinacolato)boryl]methane(cas: 78782-17-9Electric Literature of C13H26B2O4) was used in this study.

Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds. Organoboron compounds have been a cornerstone of synthetic transformations for decades. Areas such as boron-containing catalysts, metalate chemistry, photoredox methods, and boryl anions have brought significant new developments in understanding and provided new reactivity upon.Electric Literature of C13H26B2O4

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