Arora, Vinay’s team published research in Organometallics in 2020 | CAS: 1195-59-1

2,6-Pyridinedimethanol(cas: 1195-59-1) belongs to pyridine. When pyridine is adsorbed on oxide surfaces or in porous materials, the following species are commonly observed: (i) pyridine coordinated to Lewis acid sites, (ii) pyridine H-bonded to weakly acidic hydroxyls, and (iii) protonated pyridine. At high coverage, physisorbed pyridine and protonated dimers can also be observed.Application of 1195-59-1

《Solvent-Free N-Alkylation and Dehydrogenative Coupling Catalyzed by a Highly Active Pincer-Nickel Complexã€?was written by Arora, Vinay; Dutta, Moumita; Das, Kanu; Das, Babulal; Srivastava, Hemant Kumar; Kumar, Akshai. Application of 1195-59-1 And the article was included in Organometallics in 2020. The article conveys some information:

The synthesis and characterization of a pincer-Ni complex (iPr2NNN)NiCl2(MeCN) is reported here. The authors demonstrated the utility of this pincer-Ni complex (0.02 mol % and 0.002 mol %) for the catalytic N-alkylation of amines using various alcs. Under solvent-free conditions, while the highest yield (âˆ?0%) was obtained for alkylation of 2-amino pyridine with naphthyl-1-methanol, excellent turnovers (34000 TONs) was observed for alkylation of 2-amino pyridine with 4-methoxy benzyl alc. To demonstrate the synthetic utility of these systems, high yield reactions (up to 98%) were probed for representative substrates with a higher loading of the pincer-Ni catalyst (4 mol %). DFT studies indicate that while β-hydride elimination is the RDS for alc. dehydrogenation, the N-alkylated product can be formed either via hydrogenation with a rate-determining σ-bond metathesis or by alcoholysis that has imine insertion as RDS. All the corresponding resting states were observed by HRMS(ESI) anal. The labeling experiments are also complementary to DFT studies and show evidence for the involvement of benzylic C-H bond in RDS with a kCHH/kCHD of âˆ?.5. This method was applied to accomplish efficient (2000 TONS) dehydrogenative coupling leading to various benzimidazoles. After reading the article, we found that the author used 2,6-Pyridinedimethanol(cas: 1195-59-1Application of 1195-59-1)

2,6-Pyridinedimethanol(cas: 1195-59-1) belongs to pyridine. When pyridine is adsorbed on oxide surfaces or in porous materials, the following species are commonly observed: (i) pyridine coordinated to Lewis acid sites, (ii) pyridine H-bonded to weakly acidic hydroxyls, and (iii) protonated pyridine. At high coverage, physisorbed pyridine and protonated dimers can also be observed.Application of 1195-59-1

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Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts