In 2018,Szymaniak, Adam A.; Zhang, Chenlong; Coombs, John R.; Morken, James P. published 《Enantioselective synthesis of nonracemic geminal silylboronates by Pt-catalyzed hydrosilylation》.ACS Catalysis published the findings.Synthetic Route of C13H26B2O4 The information in the text is summarized as follows:
A Pt-catalyzed enantioselective hydrosilylation of alkenylboronates R1CH:CHBpin (R1 = H, alkyl, aralkyl, Me3Si, acyloxy) with hydrosilanes HSiR3 (R3 = Me2Ph), catalyzed by Pt-TADDOL complexes is described, giving chiral gem-silylboronates R1CH2CH(SiR3)(Bpin) with >93% ee and good yields. This reaction occurs with high regio- and enantioselectivity, providing a convenient route to chiral nonracemic geminal silylboronates. These compounds are useful reagents in stereoselective synthesis. After reading the article, we found that the author used Bis[(pinacolato)boryl]methane(cas: 78782-17-9Synthetic Route of C13H26B2O4)
Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds. Organoboron compounds have been a cornerstone of synthetic transformations for decades. Areas such as boron-containing catalysts, metalate chemistry, photoredox methods, and boryl anions have brought significant new developments in understanding and provided new reactivity upon.Synthetic Route of C13H26B2O4
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