The author of 《Scalable Synthesis of Sequence-Defined Oligomers via Photoflow Chemistry》 were Van De Walle, Matthias; De Bruycker, Kevin; Junkers, Tanja; Blinco, James P.; Barner-Kowollik, Christopher. And the article was published in ChemPhotoChem in 2019. Application of 156-87-6 The author mentioned the following in the article:
The development of practical routes that enable the synthesis of unimol. non-natural macromols. on multi-gram scales remains a key challenge in polymer chem. Herein, we present a continuous flow setup employing the light-induced chem. based on photocaged dienes as a controlled ligation system to establish a new platform for scalable monodisperse macromol. synthesis. 800 Mg of sequence-defined linear chains with 8 repeating units were obtained in a sequential protecting group based 2-step process. The current study demonstrates that photoflow synthesis is a viable approach to generate large quantities of monodisperse oligomers. In the experiment, the researchers used 3-Aminopropan-1-ol(cas: 156-87-6Application of 156-87-6)
3-Aminopropan-1-ol(cas: 156-87-6) belongs to anime. Milder oxidation, using reagents such as NaOCl, can remove four hydrogen atoms from primary amines of the type RCH2NH2 to form nitriles (R―C≡N), and oxidation with reagents such as MnO2 can remove two hydrogen atoms from secondary amines (R2CH―NHR′) to form imines (R2C=NR′). Tertiary amines can be oxidized to enamines (R2C=CHNR2) by a variety of reagents.Application of 156-87-6
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