《Transition-Metal-Free Homologative Cross-Coupling of Aldehydes and Ketones with Geminal Bis(boron) Compounds》 was written by Stephens, Thomas C.; Pattison, Graham. Electric Literature of C13H26B2O4This research focused ontransition metal free homologative cross coupling aldehyde ketone; geminal bis boron compound homologative cross coupling aldehyde ketone; homologated carbonyl compound preparation. The article conveys some information:
Authors report a transition-metal-free coupling of aldehydes and ketones with geminal bis(boron) building blocks which provides the coupled, homologated carbonyl compound upon oxidation This reaction not only extends an alkyl chain containing a carbonyl group, it also simultaneously introduces a new carbonyl substituent. Authors also demonstrated that enantiopure aldehydes with an enolizable stereogenic center undergo this reaction with complete retention of stereochem. In the experimental materials used by the author, we found Bis[(pinacolato)boryl]methane(cas: 78782-17-9Electric Literature of C13H26B2O4)
Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds.Electric Literature of C13H26B2O4 Organoboron compounds have been a cornerstone of synthetic transformations for decades. Areas such as boron-containing catalysts, metalate chemistry, photoredox methods, and boryl anions have brought significant new developments in understanding and provided new reactivity upon.
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