Synthetic Route of C6H7BO3In 2020 ,《A Bi-functional Second Coordination Sphere for Electrocatalytic CO2 Reduction: The Concerted Improvement by a Local Proton Source and Local Coulombic Interactions》 appeared in Chemistry Letters. The author of the article were Matsubara, Yasuo; Shimojima, Miho; Takagi, Shohei. The article conveys some information:
A homogeneous rhenium(I) electrocatalyst possessing hydroxy and ammonio groups in the second coordination sphere is reported for the reduction of carbon dioxide (CO2) to carbon monoxide, wherein the former and latter groups induce a high local concentration of protons and local coulombic interactions with a metallocarboxylate reaction intermediate, resp. In a comparison with precedent catalysts possessing single functional groups in the spheres, we found that the catalyst exhibits a concerted improvement over these single functional groups in the efficiencies of catalysis, based on exptl. standard electrode potentials for the reduction in aqueous N,N-dimethylformamide or acetonitrile solutions and the equilibrium potentials depending on the catalytic systems.2-Hydroxyphenylboronic acid(cas: 89466-08-0Synthetic Route of C6H7BO3) was used in this study.
2-Hydroxyphenylboronic acid(cas: 89466-08-0) belongs to acyl phenylboronic acid. Phenylboronic acid (PBA) has been used to extract β-blockers (a class of aminoalcohol-containing drugs) from aqueous solution, rat, and human plasma. Synthetic Route of C6H7BO3
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