Application of 873-75-6In 2019 ,《Copper-catalyzed tandem oxidative synthesis of quinazolinones from 2-aminobenzonitriles and benzyl alcohols》 appeared in Organic Chemistry Frontiers. The author of the article were Hu, Yongke; Li, Shaozhong; Li, Huaju; Li, Yanxing; Li, Jin; Duanmu, Chuansong; Li, Bindong. The article conveys some information:
An efficient and practical copper-catalyzed process for the synthesis of substituted quinazolinones I (R1 = C6H5, 4-MeOC6H4, 4-FC6H4, etc.; R2 = 6-Me, 6-OMe, 5-F, etc.) from simple and readily available 2-aminobenzonitriles and benzyl alcs. is described. This method features high functional-group tolerance and could afford a variety of desirable products in good to excellent yields with air as the sole oxidant. Moreover, a possible reaction mechanism is proposed according to the control experiments and reported literature. The results came from multiple reactions, including the reaction of (4-Bromophenyl)methanol(cas: 873-75-6Application of 873-75-6)
(4-Bromophenyl)methanol(cas: 873-75-6) undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls.Application of 873-75-6 It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde.
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