Ring enlargement reactions of homocubyl-4- and cubyl-1,4-dicarbinols was written by Higuchi, Hiroyuki. And the article was included in Advances in Strained and Interesting Organic Molecules in 1999.Computed Properties of C10H12O2 The following contents are mentioned in the article:
A review. Carbinols of cubane and homocubane derivatives were prepared by Grignard reactions in good yields. These carbinols underwent smooth C-C bond cleavage under Wagner-Meerwein conditions to give mixtures of ring enlargement products along with unexpected products, in various ratios depending on the reaction conditions. 1,4-Bishomocubane, previously believed to be much less stable than 1,3-bishomocubane both exptl. and theor., was obtained as one of major products from the electronically modified homocubyl-and cubyldicarbinols. It is indicated that the ring enlargement reactions of the present carbinols proceeds along the reaction paths in a borderline area between kinetically and thermodynamically controlled pathways. A review with 34 references This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3Computed Properties of C10H12O2).
Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Computed Properties of C10H12O2
60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3