Proton magnetic resonance spectra of cubane derivatives. I. Syntheses and spectra of mono- and 1,4-disubstituted cubanes was written by Edward, John T.; Farrell, Patrick G.; Langford, Gordon E.. And the article was included in Journal of the American Chemical Society in 1976.Name: Cubane-1,4-diyldimethanol The following contents are mentioned in the article:
The syntheses of a number of monosubstituted and 1,4-disubstituted cubanes are described, together with the measurement and anal. of their 100-MHz 1H NMR spectra. A simple additivity rule is described whereby chem. shifts in CDCl3 can be predicted to within ±0.02 ppm. Both chem. shifts and coupling constants are shown to vary with substituent electronegativity. The derived correlations allow quick and effective identification of cubane derivatives from their 1H NMR spectra, and also aid in the interpretation of the more complex spectra of less sym. cage mols. This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3Name: Cubane-1,4-diyldimethanol).
Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Name: Cubane-1,4-diyldimethanol
60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3