Proton magnetic resonance spectra of cubane derivatives. II. Aromatic solvent-induced shifts was written by Edward, John T.; Farrell, Patrick G.; Langford, Gordon E.. And the article was included in Journal of the American Chemical Society in 1976.Application of 60462-27-3 The following contents are mentioned in the article:
Aromatic solvent-induced shifts (ASIS) were measured for a number of substituted cubanes in benzene and pyridine and an additivity rule was derived which allows accurate prediction of these shifts. Protons remote from the substituent show the largest ASIS and these are shown to correlate with substituent electronegativity. Models are discussed for the nature and stereochem. of the solute-solvent interaction. The observed additive shifts arise from independent, transient 1:1 associations of solvent mols. with the electron-deficient sites of all local dipoles in the solute. This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3Application of 60462-27-3).
Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Application of 60462-27-3
60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3