Formula: C6H7NOIn 2020 ,《Synthesis and characterization of N,N-chelate manganese complexes and applications in C-N coupling reactions》 appeared in Inorganica Chimica Acta. The author of the article were Das, Kuhali; Kumar, Amol; Jana, Akash; Maji, Biplab. The article conveys some information:
Bidentate NN-ligands were derived from the reaction between aldehydes and 2-(aminomethyl)pyridine. The treatment of these ligands with Mn(CO)5Br gave complexes that are highly bench stable. The complexes were characterized by various anal. and spectral methods. Single-crystal XRD of complex Mn-2 was performed, which indicates an octahedral geometry around the metal center. The complexes efficiently catalyze the N-alkylation of anilines with alcs. under optimized reaction conditions. In the experiment, the researchers used many compounds, for example, 3-Pyridinemethanol(cas: 100-55-0Formula: C6H7NO)
3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. The basicity and metallophilic high donor number of these π-deficient systems has long favored them as ligands in metal catalysis. The last decade saw pyridine assume a stronger role as functional group for directed C–H oxidation/activation.Formula: C6H7NO
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