Application In Synthesis of (4-Bromophenyl)methanolIn 2019 ,《Iridium Supported on Phosphorus-Doped Porous Organic Polymers: Active and Recyclable Catalyst for Acceptorless Dehydrogenation and Borrowing Hydrogen Reaction》 appeared in Advanced Synthesis & Catalysis. The author of the article were Yao, Wei; Duan, Zheng-Chao; Zhang, Yilin; Sang, Xinxin; Xia, Xiao-Feng; Wang, Dawei. The article conveys some information:
Iridium-on-phosphorus-doped porous organic polymers (POP-Ir) were developed by anchoring simple iridium onto the skeleton of porous organic polymers through coordination bonds. This POP-Ir catalyst, which was thoroughly characterized by means of EDS, SEM, TEM, XRD, XPS, and FT-IR, revealed excellent catalytic activity for the reaction of di-Ph phosphinamide with benzyl alcs. through borrowing hydrogen strategy and acceptorless dehydrogenation with wide functional group tolerance. Moreover, this POP-Ir catalyst could be simply recovered and reused for at least five times without a significant loss of activity, and revealed considerable application prospects. The mechanism was investigated to further understand this POP-Ir catalytic system and transformations. Overall, the POP-Ir catalytic system has shown high activity and reusability in the borrowing hydrogen reaction between di-Ph phosphinamides and benzyl alcs. In the experiment, the researchers used (4-Bromophenyl)methanol(cas: 873-75-6Application In Synthesis of (4-Bromophenyl)methanol)
(4-Bromophenyl)methanol(cas: 873-75-6) undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls.Application In Synthesis of (4-Bromophenyl)methanol It undergoes efficient trimethylsilylation reaction with 1,1,1,3,3,3-hexamethyldisilazane in the presence of catalytic amount of aspartic acid in acetonitrile.
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