《Adaptive Se-Te Metathesis Controlled by Cucurbituril-Based Host-Guest Interaction》 was published in Chemistry – An Asian Journal in 2020. These research results belong to Liu, Cheng; Zhang, Zhiheng; Fan, Zhiyuan; He, Chaowei; Tan, Yizheng; Xu, Huaping. Electric Literature of C3H9NO The article mentions the following:
Regulating the reactivity and equilibrium of a dynamic reaction is essential for adaptive chem. and functional materials. Herein, cucurbituril-based host-guest interaction was embedded into the dynamic metathesis between diselenide and ditelluride to establish an equilibrium-adaptive system. In this system, cucurbit[6]uril (CB[6]) selectively bound with diselenide while cucurbit[7]uril (CB[7]) bound with not only diselenide but also ditelluride and exchange product. The dynamic nature of diselenide bond was locked after forming the inclusion complex with CB[6]. Based on this selective locking effect, the Se-Te products were reversed back to diselenide and ditelluride reactants, which was an equilibrium regulating process. Therefore, by combining CB[6]-based host-guest interaction and dynamic diselenide chem., the reactivity of diselenide bond and the equilibrium of Se-Te metathesis was successfully regulated. In the experiment, the researchers used 3-Aminopropan-1-ol(cas: 156-87-6Electric Literature of C3H9NO)
3-Aminopropan-1-ol(cas: 156-87-6) belongs to anime. Amines have a free lone pair with which they can coordinate to metal centers. Amine–metal bonds are weaker because amines are incapable of backbonding, but they are still important for sensing applications.While stronger than hydrogen bonds, amine–metal bonds are still weaker than both covalent and ionic bonds.Electric Literature of C3H9NO
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts