《Iron-catalyzed Versatile and Efficient C(sp2)-H Borylation》 was published in Chemistry Letters in 2019. These research results belong to Kamitani, Masahiro; Kusaka, Haruki; Yuge, Hidetaka. Recommanded Product: 2-(3,4-Dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane The article mentions the following:
The efficient C-H borylation of a variety of aromatic hydrocarbons and heteroarenes has been achieved using an iron complex bearing a quinoline-based PNN pincer ligand. Mechanistic studies revealed the formation of a bis-boryl complex, which plays a crucial role in the catalytic cycle. The methodol. allows the borylation of unactivated arenes using iron catalysts. The experimental process involved the reaction of 2-(3,4-Dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(cas: 401797-00-0Recommanded Product: 2-(3,4-Dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
2-(3,4-Dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(cas: 401797-00-0) belongs to hydroxy-containing compounds. Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this functional group.Recommanded Product: 2-(3,4-Dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Organic compounds, which are often poorly soluble in water, become water-soluble when they contain two or more hydroxy groups, as illustrated by sugars and amino acid.
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