《Metal-free and recyclable route to synthesize polysubstituted olefins via C-C bond construction from direct dehydrative coupling of alcohols or alkenes with alcohols catalyzed by sulfonic acid-functionalized ionic liquids》 was published in Advanced Synthesis & Catalysis in 2014. These research results belong to Han, Feng; Yang, Lei; Li, Zhen; Zhao, Yingwei; Xia, Chungu. HPLC of Formula: 63012-03-3 The article mentions the following:
A direct synthesis of polysubstituted olefins via construction of C-C bonds, which involves the direct dehydrative coupling of alcs. or alkenes with alcs., was realized using a series of alkanesulfonic acid group-functionalized ionic liquids (SO3H-functionalized ILs) without additives. The metal-free and recyclable catalyst system avoided the disposal and neutralization of acidic catalysts after reaction and tolerated a broad range of substrates, including benzylic, allyl, propargylic, aliphatic and aromatic or aliphatic olefins. Addnl., the catalytic system was suitable for a gram-scale preparation Preliminary mechanistic studies indicated that the C-H bond cleavage in this reaction might be involved in the rate-determining step. After reading the article, we found that the author used (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3HPLC of Formula: 63012-03-3)
(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy groups participate in the dehydration reactions that link simple biological molecules into long chains. The joining of a fatty acid to glycerol to form a triacylglycerol removes the −OH from the carboxy end of the fatty acid.HPLC of Formula: 63012-03-3
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts