In 2022,Asai, Kento; Miura, Masahiro; Hirano, Koji published an article in Journal of Organic Chemistry. The title of the article was 《Palladium-Catalyzed Cross-Coupling Reaction of Diarylmethanol Derivatives with Diborylmethane》.Category: alcohols-buliding-blocks The author mentioned the following in the article:
A palladium-catalyzed cross-coupling reaction of diarylmethanol derivatives RC(R1)OR2 (R = Ph, naphthalen-2-yl, phenanthren-9-yl, 4-phenylbenzen-1-yl; R1 = H, Ph, 4-chlorophenyl, 2H-1,3-benzodioxol-5-yl; R2 = Boc, Ph, OMe, etc.) with diborylmethane has been developed. The reaction proceeds chemoselectively to deliver the corresponding homobenzylic boronates RC(R1)CH2Bpin in good yields. In the experimental materials used by the author, we found Bis[(pinacolato)boryl]methane(cas: 78782-17-9Category: alcohols-buliding-blocks)
Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds.Category: alcohols-buliding-blocks Organoboron compounds have been a cornerstone of synthetic transformations for decades. Areas such as boron-containing catalysts, metalate chemistry, photoredox methods, and boryl anions have brought significant new developments in understanding and provided new reactivity upon.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts