On March 31, 1980, Devillers, Jean; Houalla, Doureid; Bonnet, Jean Jacques; Wolf, Robert published an article.Name: 2,2′-(tert-Butylazanediyl)diethanol The title of the article was Phosphite electrophilicity exploration: crystal and molecular structure of an eight-membered ring-containing tetrahydro-4H-1,3,6,2-dioxazaphosphocine molecule. And the article contained the following:
The mol. structure of the title compound I, determination by x-ray anal., indicates a boat-chair conformation for the rings. The transannular P-N distance is less than the sum of Van der Waals radii. CNDO/2 calculations and NMR spectra indicate that the weak transannular interaction is not an electron donation of the N atom to the P atom, but has electrostatic character. The experimental process involved the reaction of 2,2′-(tert-Butylazanediyl)diethanol(cas: 2160-93-2).Name: 2,2′-(tert-Butylazanediyl)diethanol
The Article related to crystal structure dioxazaphosphocine, transannular phosphorus nitrogen interaction, phosphite macrocyclic structure, Physical Organic Chemistry: General and other aspects.Name: 2,2′-(tert-Butylazanediyl)diethanol
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