On September 12, 2012, Taylor, Grahame N.; Prince, Philippe; Matherly, Ron; Ponnapati, Ramakrishna; Tompkins, Rose; Vaithilingam, Panchalingam published an article.Application In Synthesis of 2,2′,2”-(1,3,5-Triazinane-1,3,5-triyl)triethanol The title of the article was Identification of the Molecular Species Responsible for the Initiation of Amorphous Dithiazine Formation in Laboratory Studies of 1,3,5-Tris (hydroxyethyl)-hexahydro-s-triazine as a Hydrogen Sulfide Scavenger. And the article contained the following:
Amorphous dithiazine is produced from a solution of tris-(2-hydroxyethyl)-hexahydro-s-triazine (I) that is heavily consumed by hydrogen sulfide (H2S). Previously, it has been reported that the chem. structure of amorphous dithiazine is a polymeric structure which involves opening of the dithiazine ring. Evidence is presented here that the first step in this polymerization reaction is conversion of the terminal hydroxyl functionality into a terminal thiol. Thereafter, the thiol initiates the ring opening of the dithiazine to yield a polymeric, highly insoluble material. It has been observed that the critical chem. species in the initiation of this chain reaction is the bisulfide anion. This bisulfide anion is produced from the reaction of H2S with ethanolamine liberated in the sulfur insertion reaction undergone by tris-(2-hyroxyethyl)-hexahydro-s-triazine (I). This process has been artificially induced by the reaction of monomeric or crystalline 5-hydroxyethyldithiazine (II) and ethanolammonium hydrosulfide. The experimental process involved the reaction of 2,2′,2”-(1,3,5-Triazinane-1,3,5-triyl)triethanol(cas: 4719-04-4).Application In Synthesis of 2,2′,2”-(1,3,5-Triazinane-1,3,5-triyl)triethanol
The Article related to identification mol species responsible initiation amorphous dithiazine formation, Physical Organic Chemistry: Other Reactions, Processes, and Spectra and other aspects.Application In Synthesis of 2,2′,2”-(1,3,5-Triazinane-1,3,5-triyl)triethanol
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