On April 24, 2017, Nesterov, Dmytro S.; Alegria, Elisabete C. B. A.; Jezierska, Julia published an article.Formula: C8H19NO2 The title of the article was A new member of CuII8 family: Synthesis, structure and magnetic properties of an octanuclear copper complex with N-tert-butyldiethanolamine. And the article contained the following:
A highly-nuclear copper complex [CuII8O(tBuDea)5(HtBuDea)Cl2][CuICl2]·2H2O (1) has been prepared in a one-pot reaction of copper chloride with N-tert-butyldiethanolamine in methanol in the open air. The structure of the complex was established by single-crystal x-ray anal. The octanuclear close-packed core of 1 belongs to the {M8(μ3-X)6(μ-X)7} mol. structure type. The ESI-MS spectroscopy confirmed the stability of the whole core in methanol solution From the ESI-MS and magnetic data the divalent oxidation state of all eight coppers in the Cu8 core is proposed. Electrochem. studies were undertaken to confirm the overall CuI/CuII composition of the complex. Thermogravimetric behavior was studied and disclosed that the complex 1 is stable until 150°. The magnetic investigations revealed a dominant antiferromagnetic coupling between copper centers within the octanuclear cation. The experimental process involved the reaction of 2,2′-(tert-Butylazanediyl)diethanol(cas: 2160-93-2).Formula: C8H19NO2
The Article related to copper tertbutyldiethanolamine octanuclear complex preparation crystal structure, magnetic property electrochem copper tertbutyldiethanolamine octanuclear complex, Inorganic Chemicals and Reactions: Coordination Compounds and other aspects.Formula: C8H19NO2
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