On January 29, 2020, Mondal, Aditesh; Reddy, Kiran P.; Bertke, Jeffery A.; Kundu, Subrata published an article.Computed Properties of 96-76-4 The title of the article was Phenol Reduces Nitrite to NO at Copper(II): Role of a Proton-Responsive Outer Coordination Sphere in Phenol Oxidation. And the article contained the following:
In the view of physiol. significance, the transition-metal-mediated routes for nitrite (NO2-) to nitric oxide (NO) conversion and phenol oxidation are of prime importance. Probing the reactivity of substituted phenols toward the nitritocopper(II) cryptate complex [mC]Cu(κ2-O2N)(ClO4) (1a), (mC = aza-oxa tripodal heteroditopic cryptand) this report illustrates NO release from nitrite at Cu(II) following a proton-coupled electron transfer (PCET) pathway. Also, a different protonated state of 1a with a proton hosted in the outer coordination sphere, [mCH]Cu(κ2-O2N)(ClO4)2 (3), also reacts with substituted phenols via primary electron transfer from the phenol. Intriguingly, the alternative mechanism operative because of the presence of a proton at the remote site in 3 facilitates an unusual anaerobic pathway for phenol nitration. The experimental process involved the reaction of 2,4-Di-tert-butylphenol(cas: 96-76-4).Computed Properties of 96-76-4
The Article related to phenol mediated nitrite reduction copper cryptand nitric oxide complex, crystal structure copper zinc azaoxa cryptand nitrite complex, Inorganic Chemicals and Reactions: Coordination Compounds and other aspects.Computed Properties of 96-76-4
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