Anisimov, Anton A.; Temnikov, Maxim N.; Krizhanovskiy, Ilya; Timoshina, Ekaterina I.; Milenin, Sergey A.; Peregudov, Alexander S.; Dolgushin, Fedor M.; Muzafarov, Aziz M. published an article in 2021, the title of the article was A thiol-ene click reaction with preservation of the Si-H bond: a new approach for the synthesis of functional organosilicon compounds.COA of Formula: C10H22S And the article contains the following content:
This work presents an approach for the preparation of functional hydrosilanes. The essence of the method is a thiol-ene click reaction on vinyl or allylsilanes. In this case, the Si-H bond in the substrate mol. is not affected. The reaction proceeds with radical (AIBN) or UV initiation with yields close to quant. This makes it possible to obtain aliphatic, aromatic, carboxyl and alkoxysilyl derivatives of the corresponding silanes. Crystalline tris(3-(phenylthio)propyl) silane was obtained and characterized for the first time. In the case when the thiol-ene reaction leads to the formation of a three-dimensional network, it was possible to obtain Si-H-containing materials – a transparent monolith and an aerogel with a d. of 0.26 g ml-1. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).COA of Formula: C10H22S
The Article related to crystal structure mol hydrosilane preparation, thiolene click reaction vinyl allyl silane silicon hydrogen bond, Organometallic and Organometalloidal Compounds: Silicon Compounds and other aspects.COA of Formula: C10H22S
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