On November 15, 2022, Li, Jianmei; Yang, Ruofeng; Xu, Shuguang; Zhou, Cuiqing; Xiao, Yuan; Hu, Changwei; Tsang, Daniel C. W. published an article.Recommanded Product: 473-81-4 The title of the article was Biomass-derived polyols valorization towards glycolic acid production with high atom-economy. And the article contained the following:
Taking advantage of the inherent structure in biomass for attractive chem. synthesis with high atom economy is vital for a sustainable future but remains a great challenge. Herein, we discovered a new route for glycolic acid (GcA) synthesis using various biomass-derived polyols as feedstock with an exceptionally high atom utilization (~93%). Up to ~90 C-mol% yield of GcA could be achieved, representing the highest value among the state-of-the-art biomass valorization strategies. Strongly certified by in situ exptl. tests and multi-scale theor. calculations, it was identified that dynamical accommodation of the flexible unsaturated dangling-like Cucus-O bond in Cu2O(111) to polyols drove electron transfer from polyols to Cucus, enabling the precise activation of C1-H and C2-C3 bonds. These contributions accomplished the complex cascade reactions in polyol transformation throughout chain-sugar as intermediate with notable conformation superiority, thus generating GcA selectively. The experimental process involved the reaction of 2,3-Dihydroxypropanoic acid(cas: 473-81-4).Recommanded Product: 473-81-4
The Article related to biomass polyol glycolic acid valorization mol dynamics simulation, Industrial Organic Chemicals, Leather, Fats, and Waxes: Manufacture Of Industrial Organic Chemicals and other aspects.Recommanded Product: 473-81-4
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