Kaithal, Akash; Hoelscher, Markus; Leitner, Walter published an article in 2018, the title of the article was Catalytic Hydrogenation of Cyclic Carbonates using Manganese Complexes.SDS of cas: 78-26-2 And the article contains the following content:
Catalytic hydrogenation of cyclic carbonates to diols and methanol was achieved using a mol. catalyst based on earth-abundant manganese. The complex [Mn(CO)2(Br)][HN(C2H4PiPr2)2] 1 comprising com. available MACHO ligand is an effective pre-catalyst operating under relatively mild conditions (T=120 °C, p(H2)=30-60 bar). Upon activation with NaOtBu, the formation of coordinatively unsaturated complex [Mn(CO)2][N((C2H4PiPr2)2)] 5 was spectroscopically verified, which confirmed a kinetically competent intermediate. With the pre-activated complex, turnover numbers up to 620 and 400 were achieved for the formation of the diol and methanol, resp. Stoichiometric reactions under catalytically relevant conditions provide insight into the stepwise reduction form the CO2 level in carbonates to methanol as final product. The experimental process involved the reaction of 2-Methyl-2-propylpropane-1,3-diol(cas: 78-26-2).SDS of cas: 78-26-2
The Article related to manganese complex cyclic carbonate hydrogenation diol methanol synthesis, carbon dioxide, carbonates, hydrogenation, manganese, methanol, Industrial Organic Chemicals, Leather, Fats, and Waxes: Manufacture Of Industrial Organic Chemicals and other aspects.SDS of cas: 78-26-2
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