Bettoni, Leo; Gaillard, Sylvain; Renaud, Jean-Luc published an article in 2020, the title of the article was A phosphine-free iron complex-catalyzed synthesis of cycloalkanes via the borrowing hydrogen strategy.Synthetic Route of 111-29-5 And the article contains the following content:
Herein, a diaminocyclopentadienone iron tricarbonyl complex catalyzed synthesis of substituted cyclopentane, cyclohexane and cycloheptane compounds 2,4,6-(Me)3-3,5-(R1)2C6C(O)R (R = cyclohexyl, cyclopentyl, cycloheptyl, etc.; R1 = H, Me) using the borrowing hydrogen strategy in the presence of various substituted primary and secondary 1,n diols e.g., 2-methylpentane-1,5-diol as alkylating reagents was reported. Deuterium labeling experiments confirm that the diols were the hydride source in this cascade process. The experimental process involved the reaction of Pentane-1,5-diol(cas: 111-29-5).Synthetic Route of 111-29-5
The Article related to cycloalkane preparation diastereoselective, pentamethylphenyl ethanone diol cyclization iron catalyst, Alicyclic Compounds: Higher Members, Including Annulenes, Tropones, Tropolones, and Tropylium Compounds and other aspects.Synthetic Route of 111-29-5
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